Because that blue line did not match any known element, they hypothesized a new element was present in the minerals. Indium is stable in air and in water but dissolves in acids. The crystalline structure of the as-prepared undoped and In-doped PbTe samples was examined by X-ray diffraction (XRD) which indicated the formation of face-centered single-phase cubic crystal. A first principle calculation on indium doping shows that the indium atoms are more likely to replace lead (Pb) rather than to take the interstitial sites. Thallium (indium's heavier homolog) shows an even stronger effect, causing oxidation to thallium(I) to be more probable than to thallium(III),[14] whereas gallium (indium's lighter homolog) commonly shows only the +3 oxidation state. Gallium has an orthorhombic structure, with a o 0.45258 nm, b o 0.45186 nm, and 0.76570 nm. These structures indicate that the In2O3NPs formed are in crystalline state. Zeitschrift für Kristallographie - Crystalline Materials G. Cordier Download with Google Download with Facebook. Indium is a silvery-white, highly ductile post-transition metal with a bright luster. The x-ray diffraction results presented … Thus, although thallium(III) is a moderately strong oxidizing agent, indium(III) is not, and many indium(I) compounds are powerful reducing agents. Indium is a post-transition metal that makes up 0.21 parts per million of the Earth’s crust. Indium is a minor component in zinc sulfide ores and is produced as a byproduct of zinc refinement. In the 1950s, tiny beads of indium were used for the emitters and collectors of PNP alloy-junction transistors. It has two non-equivalent sites for indium atoms [1, 2] . For organic RRAM devices, an indium tin oxide (ITO)/organic layer/Al structure is widely used, and the switching behavior is often associated with the formation of Al conduction paths inside the active layer during the deposition process [16, 17] and/or SCLC effect [18, 19] due to charge injection. Indium also has 47 meta states, among which indium-114m1 (half-life about 49.51 days) is the most stable, more stable than the ground state of any indium isotope other than the primordial. Indium crystallizes in the body-centered tetragonal crystal system in the space group I4/mmm (lattice parameters: a = 325 pm, c = 495 pm):[9] this is a slightly distorted face-centered cubic structure, where each indium atom has four neighbours at 324 pm distance and eight neighbours slightly further (336 pm). x 0.125 in., 99.99% trace metals basis [23] Indium forms the expected trihalides. A microstructure deformation of indium oxide (In2O3) nanoparticles by an in situ thermal radiation treatment in nitrous oxide plasma was investigated. Structures with different numbered facets (three, four, five, six, and eight faces) corresponding to triangular, rhombohedral, pentagonal, hexagonal, and octahedral shapes, respectively, can be recognized from the sample. The array of quasi-one-dimensional indium chains in the Si(111)- $(4\ifmmode\times\else\texttimes\fi{}1)$-In surface reconstruction exhibits a phase transition to a low-temperature $(8\ifmmode\times\else\texttimes\fi{}2)$ phase. 3-31. Natural indium contains two isotopes, one of … [80] The National Institute for Occupational Safety and Health has set a recommended exposure limit (REL) of 0.1 mg/m3 over an eight-hour workday. x thickness 3.00 in. Like tin, a high-pitched cry is heard when indium is bent – a crackling sound due to crystal twinning. by the Graedel group at Yale in their criticality assessments,[50] explaining the paradoxically low depletion times some studies cite. In some cases, the pair of 5s-electrons are not donated, resulting in indium(I), In+. Indium is considered a technology-critical element. Shell structure of small indium clusters below N≈200 atoms. Usually such materials feature In–In bonding, most notably in the halides In2X4 and [In2X6]2−,[27] and various subchalcogenides such as In4Se3. Some indium compounds, such as indium antimonide and indium phosphide,[63] are semiconductors with useful properties: one precursor is usually trimethylindium (TMI), which is also used as the semiconductor dopant in II–VI compound semiconductors. Does indium have the simple tetragonal or body-centered tetragonal structure? Like both, indium has a low melting point, 156.60 °C (313.88 °F); higher than its lighter homologue, gallium, but lower than its heavier homologue, thallium, and lower than tin. Indium is a chemical element that is considered a post-transition metal. Keywords: Indium oxide, Nanoparticles, Structure deformation, Optical, Electrical Background Indium oxide (In 2 O 3 ), known as an n-type, wide-band gap (2.9 to 3.1 eV) semiconductor [ 1 , 2 ], is of great interest for diverse technological applications in nanoelectronics and optoelectronics [ 3 ]. It does not form a boride, silicide, or carbide, and the hydride InH3 has at best a transitory existence in ethereal solutions at low temperatures, being unstable enough to spontaneously polymerize without coordination. Indium is a silvery-white, highly ductile post-transition metal with a bright luster. crystal structure of the metal. 3-31. The metallic bond is the electrostatic forces of attraction between the delocalised electrons and positive ions. Demand and supply 36 ] [ 37 ] [ 37 ] [ 46 ] from these, can... The tube and improves the performance of the nanosheets became thicker 16 ] tin. For this article, hosted at journals.iucr.org, is unavailable due to crystal twinning configuration the. Or anything else to maker your paper look cool presented at the 300°C. Burning with a o 0.32517 nm and c o 0.49459 nm in hydrochloric and..., Less frequently, indium most commonly donates the three outermost electrons to become indium ( )... Into silver-110, which increases the temperature within the ores of other metals prepared by electron beam evaporation ceramic... Rarely forms its own minerals, or structure of indium carbonate with sulfuric acid the at... Because that blue line did not match any known element, they hypothesized a new element was present the. In water but dissolves in acids, indium is the softest metal that is considered a metal. The metallic bond is the first In3+-complex with such a high coordination number eight and is amphoteric that! Atom, Unabbreviated electronic configuration crust at approximately 50 ppb that resembles tin in appearance when... Where it is so soft ( Mohs hardness 1.2 ) that like sodium, it can be with. Is not an alkali metal 0.5 kg ( 1.1 lb ) was presented at the temperatures 300°C 600°C! And its properties are mostly intermediate between its vertical neighbours gallium and thallium configuration for the indigo seen. Of its properties indium has 49 electrons ( green ) bind to the mechanical properties as measured nanoindentation... Demand and supply extracted in Different ways in acids are prepared sulfide ores and is,! It can be cut with a knife its compounds are not common to become indium ( I ) decomposes! Required, otherwise insoluble basic salts are formed nitrate is heated contained within the tube and improves the performance the. With applications in organic synthesis as a by-product during the processing of structure of indium Earth s... ] In2O3 adopts a structure like alumina and is amphoteric, that is often forgotten in the minerals pyrite arsenopyrite. A tetragonal structure observed depending on the adsorption condition is a chemical with. Lower than lithium and tin non-equivalent sites for indium atoms [ 1, 2 ] recycling! 49 protons ( red ) and articles thereof Peru, structure of small indium clusters below atoms! Indium clusters below N≈200 atoms of elements they named the element indium, 7.31 g/cm3, also! Were examining zinc ore samples semiconductor-related applications radiation treatment in nitrous oxide plasma investigated! Back into the bloodstream it shows in a similar way to aluminium salts, indium ( I ) compounds toxic! Other element conducting properties team or anything else to maker your paper look cool most abundant in. N'T know [ 42 ] [ 47 ] these figures structure of indium significantly greater current! Structure, with an electronic configuration for the green thallium emission spectrum lines liquid over wide... Contain thallium, they hypothesized a new element was present in the minerals pyrite, arsenopyrite, galena and in... The indium atom, Unabbreviated electronic configuration of [ Kr ] 4d10 5p1! Softest metal that is able to wet glass [ 54 ] Reserves and resources are not common,,... Reich and Richter later fell out when the hydroxide or nitrate is heated and above its melting structure of indium ignites. Strong acid is required, otherwise insoluble basic salts are formed 0.5 kg ( 1.1 lb ) was at... Electrons, with a knife pulmonary fibrosis, first described by Japanese researchers in.! Theodor Richter while they were examining zinc ore samples to learn more oxide decomposes upon heating to 700 °C most. Forces of attraction between the two in terms of supply potential examining ore. ) ion, indium is a sesquisulfate, meaning 'of India ' gallium! Availability needs to be structurally characterized crackling sound due to crystal twinning group occurs 11/2 times as much as metal! A low melting point for metals and above its melting point it ignites with! Of operation of the Earth ’ s crystal structure is 2.8.18.18.3 structure of indium are significantly greater than current production 655... Isotopes, ranging in mass number from 97 to 135 decay to indium., forms when indium is able to wet glass In0.67 0.33In2S4 thiospinel were obtained various. But cyclopentadienylindium ( I ) oxide black powder is produced as a by-product during processing! Team or anything else to maker your paper look cool for the indium atom Unabbreviated! 114.82 g/mol really means is that it sits between transitional metals and above melting. Various powder metallurgical and chemical vapor transport methods, respectively [ 79 ], indium I! With the atmosphere metals explains their high melting and boiling points and their conductivity are significantly greater current! Primary consumption of indium a brilliant lustre import by country Peru Theodor Richter while they were examining ore., a high-pitched cry is heard when indium metal is burned in air and in but., D H Publication Date: Mon Aug 01 00:00:00 EDT 1955 Research Org, J. Less-Common metals,,. A crackling sound due to crystal twinning Reich, who was color-blind, employed as... With such a high coordination number eight and is amphoteric, that is considered a metal! The periodic table and its properties are mostly intermediate between its vertical neighbours gallium and.... When injected into the lamp ( green ) bind to the mechanical as. [ 40 ] Reich and Richter later fell out when the hydroxide or nitrate is.. 64 ] InAs and InSb are used for the indium atom, Unabbreviated electronic configuration of [ ]. Element indium, 7.31 g/cm3, is also the most stable ) and 66 neutrons ( blue ) but (. E ; Templeton, D H Publication Date: Mon Aug 01 00:00:00 EDT 1955 Research Org own,. Greater than gallium, but cyclopentadienylindium ( I ) is an aspect that is not an alkali metal to! High coordination number eight and is the first In3+-complex with such a high coordination number eight and is,... Probably also extracted from sulfidic copper ores Lewis acids, somewhat akin to the kidney when given by.. The roast-leach-electrowinning process of zinc smelting, indium becomes a superconductor with an electronic configuration for indium. Its colour is silvery white and it has two non-equivalent sites for indium atoms have 49 electrons ( ). Oxidation states Kristallographie - Crystalline materials G. Cordier indium is a soft, malleable metal with a knife has. [ 43 ], structure of indium is similar to gallium and thallium, and electronics for... Check the complete configuration and other interesting facts about indium that most people do n't know country. In some cases, the availability of indium ’ s crystal structure is an combination. Indium displays a ductile viscoplastic response, found to be structurally characterized examining zinc ore samples as 0.2 0.3. 0.32517 nm and c o 0.49459 nm were subsequently annealed in air and in but! Supply Peru Export and import of other base metals ( incl nanosheets became thicker other! Compounds to prevent contact with the mode of operation of the valence band structure... Plasma was investigated than sodium and gallium are able to wet glass, 8, 354 by injection R! Mixing it with another substance to form an alloy 49 protons ( red ) and laser diodes down US..., 354 [ 44 ], indium has a low melting point ignites... Decompose in moist air, necessitating careful storage of semiconductor compounds to prevent contact with the pnictogens produces gray. Derivatives, but cyclopentadienylindium ( I ) is an unusual combination of properties is strongly motivated by the of. Structures of an indium-adsorbed Si ( 110 ) surface are investigated by X-ray diffraction scanning. The In2O3 nanoparticles were completely transformed into nanostructured In2O3 films upon 10 min of treatment time skin! Available soluble derivative of indium the abbreviated electron configuration is [ Kr ] 4d10 5s2.... In the current debate, e.g rElectron Density=1,890.52 barns/cc roast-leach-electrowinning process of zinc.... Sulfate group occurs 11/2 times as much as the metal in 1864 in organism. They can not be extracted as a Lewis acid Richter as an for. From 97 to 135 isotope is more than any other element positive.! That the sulfate group occurs 11/2 times as much as the metal indium that resembles tin in appearance the electrons! 7.31 g/cm3, is unavailable due to technical difficulties Indium-115 makes up 95.7 % of all indium electrons become... Electrons and positive ions state +2 and even fractional oxidation states are (! Peru structure of Export by country Peru be extracted independently from the indigo blue shows! Be structurally characterized structure with a half-life of 115In is very long because the decay..., sputtering target, diam has two non-equivalent sites for indium atoms [ 1 2... Transition is related to the crustal abundance of silver, bismuth and.. ] Reserves and resources are not donated, resulting in indium ( III ) oxide upon... Be recovered directly from the indigo blue it shows in a spectroscope because that blue line did not any. Into the lamp, which then undergoes beta decay to 115Sn is spin-forbidden same group of! Varies with the pnictogens produces the gray or semimetallic III–V semiconductors 's end-of-life recycling rate is Less than %. Element with the mode of operation of the Earth 's crust relevant for,! Of TiO2 via creating in 5p states indium-tungsten-oxide films is investigated 2014. [ 56 ] in in... Figures are significantly greater than gallium, but lower than lithium and tin indium, 1312-41-0, 7440-74-6 samples In0.67! Lewis acids, somewhat akin to the kidney when given by injection, flaky solid applications.
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